Roberto Donadoni has named his Italy squad to face Spain with Marco Borriello, but Alessandro Del Piero, Antonio Cassano and Alberto Gilardino are out.
This is one of only two planned warm-up friendlies ahead of Euro 2008 and will take place in Spain on Wednesday night.
Gigi Buffon and Mauro Camoranesi are recalled after missing recent games with injury, while Capocannoniere Borriello of Genoa receives his second call.
However, it now looks extremely unlikely that Del Piero, Cassano or Gilardino will have a chance of breaking into the squad for the summer tournament in Austria and Switzerland.
The Azzurri will unite at the Stadio Meazza in Milan on Monday afternoon and fly out to Alicante on Tuesday for the match, which kicks off at the Luis Valero stadium in Elche at 21.00 UK time.
The other friendly will be on May 30 at the Stadio Franchi in Florence against Belgium.
Goalkeepers: Buffon (Juventus), Amelia (Livorno)
Defenders: Barzagli (Palermo), Cannavaro (Real Madrid), Grosso (Lyon), Materazzi (Inter), Panucci (Roma), Oddo (Milan), Zambrotta (Barcelona)
Midfielders: Ambrosini (Milan), Aquilani (Roma), Camoranesi (Juventus), De Rossi (Roma), Gattuso (Milan), Perrotta (Roma), Pirlo (Milan)
Forwards: Borriello (Genoa), Di Natale (Udinese), Iaquinta (Juventus), Quagliarella (Udinese), Toni (Bayern Munich).
